TY - JOUR
T1 - Rhodium-Catalyzed Insertion Reaction of PhP Group of Pentaphenylcyclopentaphosphine with Acyclic and Cyclic Disulfides
AU - Arisawa, Mieko
AU - Sawahata, Kyosuke
AU - Yamada, Tomoki
AU - Sarkar, Debayan
AU - Yamaguchi, Masahiko
N1 - Funding Information:
This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research funded by Japan Agency for Medical Research and Development (AMED), JSPS KAKENHI (Grant Nos. 17K19112 and 15H00911), Tohoku University Center for Gender Equality Promotion (TUMUG), and Morinomiyako Project for Empowering Women in Research.
PY - 2018/2/16
Y1 - 2018/2/16
N2 - Organophosphorus compounds with a phosphorus atom attached to a phenyl group and two organothio/organoseleno groups were synthesized using the rhodium-catalyzed insertion reaction of the PhP group of pentaphenylcyclopentaphosphine (PhP)5 with acyclic disulfides and diselenides. The method was applied to the synthesis of heterocyclic compounds containing the S-P-S group by the reaction of (PhP)5 and cyclic disulfides such as 1,2-dithietes, 1,2-dithiocane, 1,4,5-dithiopane, and 1,2-dithiolanes.
AB - Organophosphorus compounds with a phosphorus atom attached to a phenyl group and two organothio/organoseleno groups were synthesized using the rhodium-catalyzed insertion reaction of the PhP group of pentaphenylcyclopentaphosphine (PhP)5 with acyclic disulfides and diselenides. The method was applied to the synthesis of heterocyclic compounds containing the S-P-S group by the reaction of (PhP)5 and cyclic disulfides such as 1,2-dithietes, 1,2-dithiocane, 1,4,5-dithiopane, and 1,2-dithiolanes.
UR - http://www.scopus.com/inward/record.url?scp=85042175952&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85042175952&partnerID=8YFLogxK
U2 - 10.1021/acs.orglett.7b03825
DO - 10.1021/acs.orglett.7b03825
M3 - Article
C2 - 29412679
AN - SCOPUS:85042175952
VL - 20
SP - 938
EP - 941
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 4
ER -