Rhodium-catalyzed asymmetric coupling reaction of allylic ethers with arylboronic acids

Hiroyoshi Kiuchi, Dai Takahashi, Kenji Funaki, Tetsuo Sato, Shuichi Oi

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

An asymmetric allylic substitution of simple allylic ethers with arylboronic acids in the presence of a rhodium(I)/(R)-DTBM-SEGPHOS catalyst has been developed. The reactions proceeded smoothly at room temperature to give the corresponding branch products with excellent regioselectivities and good to excellent enantioselectivities.

Original languageEnglish
Pages (from-to)4502-4505
Number of pages4
JournalOrganic letters
Volume14
Issue number17
DOIs
Publication statusPublished - 2012 Sep 7

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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