Rhodium-catalyzed addition of phenylmethyldifluorosilane to aldehydes

Shuichi Oi; Mitsutoshi Moro; Yoshio Inoue

doi:10.1021/om0009684

Rhodium-catalyzed addition of phenylmethyldifluorosilane to aldehydes

Shuichi Oi, Mitsutoshi Moro, Yoshio Inoue

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Phenylmethyldifluorosilane reacts with aldehydes in the presence of a fluoride salt and a catalytic amount of a cationic rhodium complex, [Rh(cod)-(CH₃CN)₂]BF₄, affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.

Original language	English
Pages (from-to)	1036-1037
Number of pages	2
Journal	Organometallics
Volume	20
Issue number	6
DOIs	https://doi.org/10.1021/om0009684
Publication status	Published - 2001 Mar 19

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Rhodium-catalyzed addition of phenylmethyldifluorosilane to aldehydes",

abstract = "Phenylmethyldifluorosilane reacts with aldehydes in the presence of a fluoride salt and a catalytic amount of a cationic rhodium complex, [Rh(cod)-(CH3CN)2]BF4, affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.",

author = "Shuichi Oi and Mitsutoshi Moro and Yoshio Inoue",

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AU - Moro, Mitsutoshi

AU - Inoue, Yoshio

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Y1 - 2001/3/19

N2 - Phenylmethyldifluorosilane reacts with aldehydes in the presence of a fluoride salt and a catalytic amount of a cationic rhodium complex, [Rh(cod)-(CH3CN)2]BF4, affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.

AB - Phenylmethyldifluorosilane reacts with aldehydes in the presence of a fluoride salt and a catalytic amount of a cationic rhodium complex, [Rh(cod)-(CH3CN)2]BF4, affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.

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