Reverse spin transition triggered by a structural phase transition

Shinya Hayami, Yuji Shigeyoshi, Motoko Akita, Katsuya Inoue, Kenichi Kato, Keiichi Osaka, Masaki Takata, Ryo Kawajiri, Tadaoki Mitani, Yonezo Maeda

Research output: Contribution to journalArticlepeer-review

112 Citations (Scopus)

Abstract

(Figure Presented) Reverse spin crossover (RSCO), the reversible spin transition from the high- to the low-spin state upon heating, was observed in [Co(Cn-terpy)2](BF4)2 (C n-terpy = terpyridine) equipped with a long alkoxy chain (AC) of n = 14 or 16 methylene units (see picture). The wide thermal hysteresis of the RSCO around room temperature could allow such compounds to be used as molecular switches.

Original languageEnglish
Pages (from-to)4899-4903
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number31
DOIs
Publication statusPublished - 2005 Aug 5
Externally publishedYes

Keywords

  • Cobalt
  • Magnetic properties
  • N ligands
  • Spin crossover
  • Tridentate ligands

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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