Reusable and sustainable nanostructured skeleton catalyst: Heck reaction with nanoporous metallic glass Pd (PdNPore) as a support, stabilizer and ligand-free catalyst

Tetsuro Kaneko, Shinya Tanaka, Naoki Asao, Yoshinori Yamamoto, Mingwei Chen, Wei Zhang, Akihisa Inoue

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

Nanoporous metallic glass palladium (PdNPore), which was fabricated by de-alloying of a glassy metallic alloy Pd30Ni50P 20, exhibited a remarkable catalytic activity for the Heck reaction of versatile aryl iodides and aryl bromides. Moreover, the PdNPore can be reused several times without a significant loss of catalytic activity, and the PdNPore has ahigher resistance to leaching than palladium black and palladium on carbon.

Original languageEnglish
Pages (from-to)2927-2932
Number of pages6
JournalAdvanced Synthesis and Catalysis
Volume353
Issue number16
DOIs
Publication statusPublished - 2011 Nov

Keywords

  • Heck reaction
  • metallic glass
  • nanoporous materials
  • palladium
  • skeleton catalyst

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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