Abstract
Ionic fragments of BF3 produced by the B 1sa2 photoexcitation have been mass analyzed in coincidence with the resonance spectator B KVV Auger electrons. Dissociation from the BF3+ states with one outer-valence hole produces only BF2+, while dissociation from the BF3+ states with two outer-valence holes and one electron excited to the a2 orbital produces predominantly B+. Dissociation producing B+ or F+ from the BF3+ states with one outer-valence hole, one inner-valence hole, and one excited electron occurs in competition with the autoionization.
| Original language | English |
|---|---|
| Pages (from-to) | R5-R8 |
| Journal | Physical Review A |
| Volume | 46 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1992 Jan 1 |
| Externally published | Yes |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
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Ueda, K., Chiba, H., Sato, Y., Hayaishi, T., Shigemasa, E., & Yagishita, A. (1992). Resonance-Auger-electronphotoion coincidence studies on state-to-state dissociation dynamics of inner-shell-excited BF3. Physical Review A, 46(1), R5-R8. https://doi.org/10.1103/PhysRevA.46.R5