Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex

Masahiro Terada, Koichi Mikami, Takeshi Nakai

Research output: Contribution to journalArticlepeer-review

98 Citations (Scopus)

Abstract

The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.

Original languageEnglish
Pages (from-to)1623-1624
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
Publication statusPublished - 1990 Dec 1
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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