Relay catalysis by a metal-complex/brønsted acid binary system in a tandem isomerization/carbon-carbon bond forming sequence

Keiichi Sorimachi, Masahiro Terada

Research output: Contribution to journalArticlepeer-review

136 Citations (Scopus)

Abstract

A one-pot tandem isomerization/carbon-carbon bond forming sequence catalyzed by a ruthenium complex/Brønsted acid binary system is demonstrated. The method enables the use of readily available allylamides to deliver reactive imines under relay catalysis using a binary catalytic system. Subsequent Brønsted acid catalyzed carbon-carbon bond forming reactions of the generated imines with nucleophilic components afforded Friedel-Crafts and Mannich products in good yields.

Original languageEnglish
Pages (from-to)14452-14453
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number44
DOIs
Publication statusPublished - 2008 Nov 5

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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