Relationships among chemical composition, lattice constants, and acoustic properties for Ca3Ta(Ga1−xAlx)3Si2O14 single crystals

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2 Citations (Scopus)

Abstract

The relationship among lattice constant a, Al content, and acoustic properties were experimentally examined using a plate specimen perpendicular to Y-axis prepared from Ca3Ta(Ga0.75Al0.25)3Si2O14 [CTGAS(0.25)] single crystal grown by Czochralski method. As the acoustic properties, leaky surface acoustic wave (LSAW) velocities with different propagation directions, X- and Z-propagations, and longitudinal wave velocity propagating along Y-axis direction were measured by the line-focus-beam/plane-wave ultrasonic-material-characterization (LFB/PW-UMC) system. The measured results of LSAW velocity distributions revealed inhomogeneity in radial direction of the crystal ingot exhibiting lower velocity area at the center of the ingot. In addition, the distributions of lattice constant a and chemical composition (especially Al content) were measured along the radial direction. Abnormal changes suggesting existence of residual stresses concentrated on the central part of the crystal ingot other than the effect of chemical composition change were detected from the relationships among the measured parameters.

Original languageEnglish
Pages (from-to)376-381
Number of pages6
JournalJournal of Crystal Growth
Volume468
DOIs
Publication statusPublished - 2017 Jun 15

Keywords

  • A1. Characterization
  • A2. Czochralski method
  • B1. Oxides
  • B2. Piezoelectric materials

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Materials Chemistry

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