Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess

Itaru Sato; Daisuke Omiya; Hiroyoshi Igarashi; Keiichi Kato; Yoshihiro Ogi; Koichi Tsukiyama; Kenso Soai

doi:10.1016/S0957-4166(03)00164-2

Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess

Itaru Sato, Daisuke Omiya, Hiroyoshi Igarashi, Keiichi Kato, Yoshihiro Ogi, Koichi Tsukiyama, Kenso Soai

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

Experimental and kinetic analysis of asymmetric autocatalysis with amplification of ee in the enantioselective addition of diisopropylzinc to 2-alkynylpyrimidine-5-carbaldehyde using chiral 2-alkynyl-5-pyrimidyl alkanol with low ee's are described.

Original language	English
Pages (from-to)	975-979
Number of pages	5
Journal	Tetrahedron Asymmetry
Volume	14
Issue number	8
DOIs	https://doi.org/10.1016/S0957-4166(03)00164-2
Publication status	Published - 2003 Apr 18

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess. / Sato, Itaru; Omiya, Daisuke; Igarashi, Hiroyoshi; Kato, Keiichi; Ogi, Yoshihiro; Tsukiyama, Koichi; Soai, Kenso.

In: Tetrahedron Asymmetry, Vol. 14, No. 8, 18.04.2003, p. 975-979.

Research output: Contribution to journal › Article › peer-review

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abstract = "Experimental and kinetic analysis of asymmetric autocatalysis with amplification of ee in the enantioselective addition of diisopropylzinc to 2-alkynylpyrimidine-5-carbaldehyde using chiral 2-alkynyl-5-pyrimidyl alkanol with low ee's are described.",

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AU - Kato, Keiichi

AU - Ogi, Yoshihiro

AU - Tsukiyama, Koichi

AU - Soai, Kenso

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