TY - JOUR
T1 - Regiospecific synthesis of 2-allyl-1,2,3-triazoles by palladium-catalyzed 1,3-dipolar cycloaddition
AU - Kamijo, Shin
AU - Jin, Tienan
AU - Huo, Zhibao
AU - Yamamoto, Yoshinori
N1 - Copyright:
Copyright 2005 Elsevier B.V., All rights reserved.
PY - 2002/12/23
Y1 - 2002/12/23
N2 - 2-Allyl-1,2,3-triazoles were prepared by the palladium-catalyzed three component coupling (TCC) reaction of alkynes, allyl methyl carbonate and trimethylsilyl azide. A π-allylpalladium azide complex, which undergoes the 1,3-dipolar cycloaddition with alkynes, is proposed as a key intermediate in the TCC reaction.
AB - 2-Allyl-1,2,3-triazoles were prepared by the palladium-catalyzed three component coupling (TCC) reaction of alkynes, allyl methyl carbonate and trimethylsilyl azide. A π-allylpalladium azide complex, which undergoes the 1,3-dipolar cycloaddition with alkynes, is proposed as a key intermediate in the TCC reaction.
UR - http://www.scopus.com/inward/record.url?scp=0037164658&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037164658&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(02)02206-2
DO - 10.1016/S0040-4039(02)02206-2
M3 - Article
AN - SCOPUS:0037164658
SN - 0040-4039
VL - 43
SP - 9707
EP - 9710
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 52
ER -