Regiospecific rearrangement of hydroxylamines to secondary amines using diisobutylaluminum hydride

Hidetsura Cho, Kenji Sugimoto, Yusuke Iwama, Nakako Mitsuhashi, Kentaro Okano, Hidetoshi Tokuyama

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A systematic investigation of a reductive ring-expansion reaction of N-monosubstituted hydroxylamines with diisobutylaluminum hydride (DIBALH) was carried out. The reaction regiospecifically provided a variety of bicyclic or tricyclic heterocycles or linear secondary amines containing nitrogen attached to an aromatic ring.

Original languageEnglish
Pages (from-to)1633-1644
Number of pages12
JournalHeterocycles
Volume82
Issue number2
DOIs
Publication statusPublished - 2010 Feb 28

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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