Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Masaaki Suzuki, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

51 Citations (Scopus)

Abstract

Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.

Original languageEnglish
Pages (from-to)4597-4601
Number of pages5
JournalTetrahedron Letters
Volume44
Issue number24
DOIs
Publication statusPublished - 2003 Jun 9

Keywords

  • Expanded porphyrin
  • Nucleophilic substitution
  • Porphyrinoids

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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