Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Masaaki Suzuki; Soji Shimizu; Ji Young Shin; Atsuhiro Osuka

doi:10.1016/S0040-4039(03)00950-X

Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Masaaki Suzuki, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.

Original language	English
Pages (from-to)	4597-4601
Number of pages	5
Journal	Tetrahedron Letters
Volume	44
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4039(03)00950-X
Publication status	Published - 2003 Jun 9

Keywords

Expanded porphyrin
Nucleophilic substitution
Porphyrinoids

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.",

keywords = "Expanded porphyrin, Nucleophilic substitution, Porphyrinoids",

author = "Masaaki Suzuki and Soji Shimizu and Shin, {Ji Young} and Atsuhiro Osuka",

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language = "English",

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T1 - Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

AU - Suzuki, Masaaki

AU - Shimizu, Soji

AU - Shin, Ji Young

AU - Osuka, Atsuhiro

PY - 2003/6/9

Y1 - 2003/6/9

N2 - Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.

AB - Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.

KW - Expanded porphyrin

KW - Nucleophilic substitution

KW - Porphyrinoids

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U2 - 10.1016/S0040-4039(03)00950-X

DO - 10.1016/S0040-4039(03)00950-X

M3 - Article

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SP - 4597

EP - 4601

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 24

ER -

Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Abstract

Keywords

ASJC Scopus subject areas

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