Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions

S. Oi; M. Nomura; T. Aiko; Y. Inoue

doi:10.1016/S1381-1169(96)00282-8

Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions

S. Oi, M. Nomura, T. Aiko, Y. Inoue

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

91 Citations (Scopus)

Abstract

The cationic palladium(II) complex [Pd(MeCN)₂(PPh₃)₂](BF₄)₂ was found to be an active catalyst for hydroesterification of styrene using CO and methanol under very mild conditions. The system, Pd(OAc)₂-PPh₃-p- toluenesulfonic acid, which should give rise to a cationic species in situ, was also effective to produce the branched ester regioselectively in an excellent yield at ambient temperature. Asymmetric hydroesterification of styrene by the use of chiral phosphines as ligands was also studied.

Original language	English
Pages (from-to)	289-295
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	115
Issue number	2
DOIs	https://doi.org/10.1016/S1381-1169(96)00282-8
Publication status	Published - 1997 Jan 29

Keywords

Carbon monoxide
Hydroesterification
Palladium
Styrene

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

Access to Document

10.1016/S1381-1169(96)00282-8

Fingerprint Dive into the research topics of 'Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions'. Together they form a unique fingerprint.

Cite this

@article{c6e5d0bc64d24aad999efdd870867a02,

title = "Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions",

abstract = "The cationic palladium(II) complex [Pd(MeCN)2(PPh3)2](BF4)2 was found to be an active catalyst for hydroesterification of styrene using CO and methanol under very mild conditions. The system, Pd(OAc)2-PPh3-p- toluenesulfonic acid, which should give rise to a cationic species in situ, was also effective to produce the branched ester regioselectively in an excellent yield at ambient temperature. Asymmetric hydroesterification of styrene by the use of chiral phosphines as ligands was also studied.",

keywords = "Carbon monoxide, Hydroesterification, Palladium, Styrene",

author = "S. Oi and M. Nomura and T. Aiko and Y. Inoue",

year = "1997",

month = jan,

day = "29",

doi = "10.1016/S1381-1169(96)00282-8",

language = "English",

volume = "115",

pages = "289--295",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions

AU - Oi, S.

AU - Nomura, M.

AU - Aiko, T.

AU - Inoue, Y.

PY - 1997/1/29

Y1 - 1997/1/29

N2 - The cationic palladium(II) complex [Pd(MeCN)2(PPh3)2](BF4)2 was found to be an active catalyst for hydroesterification of styrene using CO and methanol under very mild conditions. The system, Pd(OAc)2-PPh3-p- toluenesulfonic acid, which should give rise to a cationic species in situ, was also effective to produce the branched ester regioselectively in an excellent yield at ambient temperature. Asymmetric hydroesterification of styrene by the use of chiral phosphines as ligands was also studied.

AB - The cationic palladium(II) complex [Pd(MeCN)2(PPh3)2](BF4)2 was found to be an active catalyst for hydroesterification of styrene using CO and methanol under very mild conditions. The system, Pd(OAc)2-PPh3-p- toluenesulfonic acid, which should give rise to a cationic species in situ, was also effective to produce the branched ester regioselectively in an excellent yield at ambient temperature. Asymmetric hydroesterification of styrene by the use of chiral phosphines as ligands was also studied.

KW - Carbon monoxide

KW - Hydroesterification

KW - Palladium

KW - Styrene

UR - http://www.scopus.com/inward/record.url?scp=0031029748&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031029748&partnerID=8YFLogxK

U2 - 10.1016/S1381-1169(96)00282-8

DO - 10.1016/S1381-1169(96)00282-8

M3 - Article

AN - SCOPUS:0031029748

VL - 115

SP - 289

EP - 295

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

SN - 1381-1169

IS - 2

ER -