Regioselective generation and stereoselective [1 + 2] cycloaddition of substituted vinylcarbenes

Hidetosbi Tokuyama, Taro Yamada, Eiichi Nakamura

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Thermolysis of a mixture of the substituted cyclopropenone acetal la and an electron-deficient olefin produces the cyclopropane 5 as a predominant (86-100%) structural isomer through [1+2] cycloaddition of the vinylcarbene isomer 2 via an endo transition state 4.

Original languageEnglish
Pages (from-to)589-591
Number of pages3
JournalSynlett
Volume1993
Issue number8
DOIs
Publication statusPublished - 1993 Aug
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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