Abstract
Transmetallation of 2-tributylstannylbuta-1,3-diene with SnCl4 followed by Lewis base promoted addition of the resulting 1-trichlorostannyl-2,3-butadiene to aldehydes in the presence of DMF allows their buta-1,3-dienylation to take place at the C2 position with complete regioselectivity in high yields.
| Original language | English |
|---|---|
| Pages (from-to) | 1109-1111 |
| Number of pages | 3 |
| Journal | Synlett |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 1999 Jan 1 |
| Externally published | Yes |
Keywords
- Buta-1,3-dienes
- Buta-1,3-dienylations
- Lewis base promoted reaction
- Tin compounds
- Transmetallations
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Luo, M., Iwabuchi, Y., & Hatakeyama, S. (1999). Regioselective buta-1,3-dienylation of aldehydes via transmetallation of 2-tributylstannylbuta-1,3-diene. Synlett, (7), 1109-1111. https://doi.org/10.1055/s-1999-2787