Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Martin Fleck; Cheng Yang; Takehiko Wada; Yoshihisa Inoue; Thorsten Bach

doi:10.1039/b613985j

Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Martin Fleck, Cheng Yang, Takehiko Wada, Yoshihisa Inoue, Thorsten Bach

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

Original language	English
Pages (from-to)	822-824
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b613985j
Publication status	Published - 2007 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Inoue, Yoshihisa

AU - Bach, Thorsten

PY - 2007/1/1

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AB - The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

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Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Abstract

ASJC Scopus subject areas

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