Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Martin Fleck, Cheng Yang, Takehiko Wada, Yoshihisa Inoue, Thorsten Bach

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

Original languageEnglish
Pages (from-to)822-824
Number of pages3
JournalChemical Communications
Issue number8
DOIs
Publication statusPublished - 2007 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium'. Together they form a unique fingerprint.

  • Cite this