Regio- and Stereospecific Preparation of β-(Alkylthio)alkenyl-1,3,2-benzodioxaboroles by Nickel-Catalyzed Hydroboration of Thioacetylenes with Catecholborane

Ilya D. Gridnev, Norio Miyaura, Akira Suzuki

Research output: Contribution to journalComment/debatepeer-review

85 Citations (Scopus)

Abstract

Hydroboration of 1-(alkylthio)-1-alkynes with catecholborane 1 in the presence of 3 mol % of NiCl2(dppe) or NiCl2(dppp) proceeds regio-and stereospecifically, giving excellent yields of [(E)-1-(alkylthio)-1-alken-2-yl]-1,3,2-benzodioxaboroles 2 under mild conditions.

Original languageEnglish
Pages (from-to)589-592
Number of pages4
JournalOrganometallics
Volume12
Issue number2
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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