Abstract
Electrochemical measurements on a series of [NBu4][Ln(III)Pc2] ([NBu4]=tetra(n-butyl)ammonium; Ln=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Er, Yb, and Lu; Pc=phthalocyanine) are reported. The first and second oxidation potentials decrease linearly with a decrease in ionic radii of the center metals, while the reduction potentials showed no observable change. A few complexes of earlier lanthanides showed irreversible redox couples at the second oxidation potentials.
| Original language | English |
|---|---|
| Pages (from-to) | 397-400 |
| Number of pages | 4 |
| Journal | Chemical Physics Letters |
| Volume | 165 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1990 Jan 26 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Konami, H., Hatano, M., Kobayashi, N., & Osa, T. (1990). Redox potentials of a series of lanthanide-bisphthalocyanine sandwich complexes. Chemical Physics Letters, 165(5), 397-400. https://doi.org/10.1016/0009-2614(90)85448-L