TY - JOUR
T1 - Redox potentials of a series of lanthanide-bisphthalocyanine sandwich complexes
AU - Konami, Hideo
AU - Hatano, Masahiro
AU - Kobayashi, Nagao
AU - Osa, Tetsuo
PY - 1990/1/26
Y1 - 1990/1/26
N2 - Electrochemical measurements on a series of [NBu4][Ln(III)Pc2] ([NBu4]=tetra(n-butyl)ammonium; Ln=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Er, Yb, and Lu; Pc=phthalocyanine) are reported. The first and second oxidation potentials decrease linearly with a decrease in ionic radii of the center metals, while the reduction potentials showed no observable change. A few complexes of earlier lanthanides showed irreversible redox couples at the second oxidation potentials.
AB - Electrochemical measurements on a series of [NBu4][Ln(III)Pc2] ([NBu4]=tetra(n-butyl)ammonium; Ln=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Er, Yb, and Lu; Pc=phthalocyanine) are reported. The first and second oxidation potentials decrease linearly with a decrease in ionic radii of the center metals, while the reduction potentials showed no observable change. A few complexes of earlier lanthanides showed irreversible redox couples at the second oxidation potentials.
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U2 - 10.1016/0009-2614(90)85448-L
DO - 10.1016/0009-2614(90)85448-L
M3 - Article
AN - SCOPUS:0000452925
VL - 165
SP - 397
EP - 400
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 5
ER -