Recombination of an Fe-Si-P linkage to an Fe-P-Si linkage through an isolable intermediate phosphasilaferracyclopropane

Masaaki Okazaki, Takahiko Yoshitomi, Junpei Naito, Akira Sato, Takashi Komuro, Hiromi Tobita

Research output: Contribution to journalShort surveypeer-review

6 Citations (Scopus)

Abstract

Phosphasilaferracycle [Cp*(CO)Fe{κ2Si,P-SiMe 2PPh2}], prepared upon irradiation of [Cp*(CO) 2FeSiMe2PPh2], was converted to [Cp*(CO)2FeP(Ph)SiMe2Ph] under mild conditions. The unusual recombination of the iron, silicon, and phosphorus cores could be achieved through a sequence of 1,2- and 1,3-group migrations in an FeSiP system.

Original languageEnglish
Pages (from-to)17674-17675
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number52
DOIs
Publication statusPublished - 2008 Dec 31

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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