Recognition of planar chirality by cyclodextrins

Koji Kano; Ryoko Takaoka; Masayuki Sato; Masahiko Yamaguchi

doi:10.1246/cl.1999.1337

Recognition of planar chirality by cyclodextrins

Koji Kano, Ryoko Takaoka, Masayuki Sato, Masahiko Yamaguchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

Abstract

Recognition of planar chirality of 14-hydroxy-12-oxabicyclo[9.2.2]pentadecane-1 (14), 11(15)-diene-1,13-dione (C8) and 16-hydroxy-14-oxabicyclo[11.2.2]heptadecane-1(16),13(17)-diene-2,15-dione (C10) by native and O-methylated cyclodextrins has been studied by NMR spectroscopy. The cyclodextrins prefer the (R)-enantiomers of C8 and C10, which might well fit with asymmetrically twisted cavities of cyclodextrins.

Original language	English
Pages (from-to)	1337-1338
Number of pages	2
Journal	Chemistry Letters
Issue number	12
DOIs	https://doi.org/10.1246/cl.1999.1337
Publication status	Published - 1999

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title = "Recognition of planar chirality by cyclodextrins",

abstract = "Recognition of planar chirality of 14-hydroxy-12-oxabicyclo[9.2.2]pentadecane-1 (14), 11(15)-diene-1,13-dione (C8) and 16-hydroxy-14-oxabicyclo[11.2.2]heptadecane-1(16),13(17)-diene-2,15-dione (C10) by native and O-methylated cyclodextrins has been studied by NMR spectroscopy. The cyclodextrins prefer the (R)-enantiomers of C8 and C10, which might well fit with asymmetrically twisted cavities of cyclodextrins.",

author = "Koji Kano and Ryoko Takaoka and Masayuki Sato and Masahiko Yamaguchi",

year = "1999",

doi = "10.1246/cl.1999.1337",

language = "English",

pages = "1337--1338",

journal = "Chemistry Letters",

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publisher = "Chemical Society of Japan",

number = "12",

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AU - Kano, Koji

AU - Takaoka, Ryoko

AU - Sato, Masayuki

AU - Yamaguchi, Masahiko

PY - 1999

Y1 - 1999

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Recognition of planar chirality by cyclodextrins

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