Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds

Shintaro Ishida; Takeaki Iwamoto

doi:10.1016/j.ccr.2015.11.007

Recent advances in η²-disilene and η²-disilyne mononuclear transition metal complexes and related compounds

Shintaro Ishida, Takeaki Iwamoto

SCI - Chemistry

Research output: Contribution to journal › Review article › peer-review

3 Citations (Scopus)

Abstract

Recent progress of η²-disilene and η²-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η²-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, ²⁹Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η²-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R₂SiCR'₂), silanimines (R₂SiNR'), silanones (R₂SiO) and related doubly-bonded germanium and tin compounds as η²-ligands are briefly summarized.

Original language	English
Pages (from-to)	34-63
Number of pages	30
Journal	Coordination Chemistry Reviews
Volume	314
DOIs	https://doi.org/10.1016/j.ccr.2015.11.007
Publication status	Published - 2016 May 1

Keywords

Disilene
Disilyne
Group-14 elements
Silene
Transition metal complex

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ccr.2015.11.007

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title = "Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds",

abstract = "Recent progress of η2-disilene and η2-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η2-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, 29Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η2-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R2SiCR'2), silanimines (R2SiNR'), silanones (R2SiO) and related doubly-bonded germanium and tin compounds as η2-ligands are briefly summarized.",

keywords = "Disilene, Disilyne, Group-14 elements, Silene, Transition metal complex",

author = "Shintaro Ishida and Takeaki Iwamoto",

note = "Funding Information: Preparation of this manuscript was supported in part by JSPS KAKENHI Grant Number 24655024 (T.I.), 15K13634 (T.I.), 25708004 (S.I.) and 15K13635 (S.I.), MEXT KAKENHI (Grant-in-Aid for Scientific Research on Innovative Areas “Stimuli-responsive Chemical Species”) Grant Number 24109004 (T.I.). Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2016",

month = may,

day = "1",

doi = "10.1016/j.ccr.2015.11.007",

language = "English",

volume = "314",

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journal = "Coordination Chemistry Reviews",

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T1 - Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds

AU - Ishida, Shintaro

AU - Iwamoto, Takeaki

N1 - Funding Information: Preparation of this manuscript was supported in part by JSPS KAKENHI Grant Number 24655024 (T.I.), 15K13634 (T.I.), 25708004 (S.I.) and 15K13635 (S.I.), MEXT KAKENHI (Grant-in-Aid for Scientific Research on Innovative Areas “Stimuli-responsive Chemical Species”) Grant Number 24109004 (T.I.). Publisher Copyright: © 2015 Elsevier B.V.

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Recent progress of η2-disilene and η2-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η2-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, 29Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η2-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R2SiCR'2), silanimines (R2SiNR'), silanones (R2SiO) and related doubly-bonded germanium and tin compounds as η2-ligands are briefly summarized.

AB - Recent progress of η2-disilene and η2-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η2-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, 29Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η2-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R2SiCR'2), silanimines (R2SiNR'), silanones (R2SiO) and related doubly-bonded germanium and tin compounds as η2-ligands are briefly summarized.

KW - Disilene

KW - Disilyne

KW - Group-14 elements

KW - Silene

KW - Transition metal complex

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