TY - JOUR
T1 - Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds
AU - Ishida, Shintaro
AU - Iwamoto, Takeaki
N1 - Funding Information:
Preparation of this manuscript was supported in part by JSPS KAKENHI Grant Number 24655024 (T.I.), 15K13634 (T.I.), 25708004 (S.I.) and 15K13635 (S.I.), MEXT KAKENHI (Grant-in-Aid for Scientific Research on Innovative Areas “Stimuli-responsive Chemical Species”) Grant Number 24109004 (T.I.).
Publisher Copyright:
© 2015 Elsevier B.V.
PY - 2016/5/1
Y1 - 2016/5/1
N2 - Recent progress of η2-disilene and η2-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η2-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, 29Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η2-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R2SiCR'2), silanimines (R2SiNR'), silanones (R2SiO) and related doubly-bonded germanium and tin compounds as η2-ligands are briefly summarized.
AB - Recent progress of η2-disilene and η2-disilylne mononuclear transition metal complexes and related complexes are summarized. Although examples for disilene-transition metal complexes are still limited for group 4, 6, 8, 10 and 11 metals, η2-disilene transition metals complexes have been synthesized by various synthetic methods and structural characteristics are well discussed by using X-ray diffraction analysis, 29Si NMR resonances and Dewar-Chatt-Duncanson model. Reactions of these complexes have been also investigated. Very recently, η2-disilyne-group 10 metal complexes have been synthesized. In addition, transition metal complexes with doubly-bonded silicon compounds such as silenes (R2SiCR'2), silanimines (R2SiNR'), silanones (R2SiO) and related doubly-bonded germanium and tin compounds as η2-ligands are briefly summarized.
KW - Disilene
KW - Disilyne
KW - Group-14 elements
KW - Silene
KW - Transition metal complex
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U2 - 10.1016/j.ccr.2015.11.007
DO - 10.1016/j.ccr.2015.11.007
M3 - Review article
AN - SCOPUS:84960805676
VL - 314
SP - 34
EP - 63
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
ER -