Reactivity and characterization of adsorbed oxygen on SrTi(1-x)Mg(x)O(3- δ) catalysts for oxidative coupling of methane

Keiichi Tomishige, Xiao Hong Li, Kaoru Fujimoto

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The reactivity of oxygen species adsorbed on SrTi(1-x)Mg(x)O(3-δ) catalysts with methane was investigated. Temperature programmed desorption of oxygen, temperature programmed surface reaction of methane, and electron spin resonance were used for the characterization of oxygen species. It is suggested that the adsorption site is formed by the substitution of Ti4+ in Sr-Ti perovskite-type oxides with added Mg2+. It was found that this oxygen species was able to convert methane to ethane at a temperature as low as 550 K. Without CO2 on the surface, C2 hydrocarbons were formed with high selectivity in the CH4 + O2 reaction. On the other hand, CO and CO2 were formed on the catalyst with CO2 pre-adsorption.

Original languageEnglish
Pages (from-to)3039-3045
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume1
Issue number12
DOIs
Publication statusPublished - 1999 Jun 15
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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