Abstract
Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.
Original language | English |
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Pages (from-to) | 588-590 |
Number of pages | 3 |
Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
Volume | 191 |
Issue number | 4 |
DOIs | |
Publication status | Published - 2016 Apr 2 |
Externally published | Yes |
Keywords
- Dialumanes
- alumylene
- bulky substituents
- cycloaddition
- dialumenes
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Inorganic Chemistry