Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.
|Number of pages||3|
|Journal||Phosphorus, Sulfur and Silicon and the Related Elements|
|Publication status||Published - 2016 Apr 2|
- bulky substituents
ASJC Scopus subject areas
- Organic Chemistry
- Inorganic Chemistry