Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

Tomohiro Agou, Koichi Nagata, Takahiro Sasamori, Norihiro Tokitoh

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.

Original languageEnglish
Pages (from-to)588-590
Number of pages3
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume191
Issue number4
DOIs
Publication statusPublished - 2016 Apr 2
Externally publishedYes

Keywords

  • Dialumanes
  • alumylene
  • bulky substituents
  • cycloaddition
  • dialumenes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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