Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

Tomohiro Agou; Koichi Nagata; Takahiro Sasamori; Norihiro Tokitoh

doi:10.1080/10426507.2015.1128912

Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

Tomohiro Agou, Koichi Nagata, Takahiro Sasamori, Norihiro Tokitoh

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy₃)₂] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.

Original language	English
Pages (from-to)	588-590
Number of pages	3
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	191
Issue number	4
DOIs	https://doi.org/10.1080/10426507.2015.1128912
Publication status	Published - 2016 Apr 2
Externally published	Yes

Keywords

Dialumanes
alumylene
bulky substituents
cycloaddition
dialumenes

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426507.2015.1128912

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title = "Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species",

abstract = "Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.",

keywords = "Dialumanes, alumylene, bulky substituents, cycloaddition, dialumenes",

author = "Tomohiro Agou and Koichi Nagata and Takahiro Sasamori and Norihiro Tokitoh",

note = "Funding Information: This work was partially supported by JSPS KAKENHI (Nos. 24109013, 24550048, 2662028, and 15H05477), MEXT Project of Integrated Research on Chemical Synthesis from the Ministry of Education, Culture, Sports, Science and Technology, Japan, the and #x201c;Molecular Systems Research and #x201d; project of RIKEN Advanced Science Institute. Koichi Nagata acknowledges financial support by Grants-in-Aid for JSPS Fellows (No. 252926). Publisher Copyright: {\textcopyright} 2016 Taylor and Francis Group, LLC.",

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doi = "10.1080/10426507.2015.1128912",

language = "English",

volume = "191",

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T1 - Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

AU - Agou, Tomohiro

AU - Nagata, Koichi

AU - Sasamori, Takahiro

AU - Tokitoh, Norihiro

N1 - Funding Information: This work was partially supported by JSPS KAKENHI (Nos. 24109013, 24550048, 2662028, and 15H05477), MEXT Project of Integrated Research on Chemical Synthesis from the Ministry of Education, Culture, Sports, Science and Technology, Japan, the and #x201c;Molecular Systems Research and #x201d; project of RIKEN Advanced Science Institute. Koichi Nagata acknowledges financial support by Grants-in-Aid for JSPS Fellows (No. 252926). Publisher Copyright: © 2016 Taylor and Francis Group, LLC.

PY - 2016/4/2

Y1 - 2016/4/2

N2 - Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.

AB - Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.

KW - Dialumanes

KW - alumylene

KW - bulky substituents

KW - cycloaddition

KW - dialumenes

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JO - Phosphorus, Sulfur and Silicon and the Related Elements

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SN - 1042-6507

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ER -

Reactivities of a barrelene-type dialumane as an equivalent of an Al=Al doubly-bonded species

Abstract

Keywords

ASJC Scopus subject areas

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