Reactions of ( THF) W( CO) 5 with some diphosphenes carrying bulky aryl and phenoxy groups

De Lie An, Kozo Toyota, Masafumi Yasunami, Masaaki Yoshifuji

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The reaction of (THF)W(CO)5 (THF = tetrahydrofuran) with asymmetrical diphosphenes carrying bulky aryl and phenoxy groups gave end-on-type complexes on either phosphorus atom. One of the complexes was analyzed by X-ray crystallography indicating that the major complex suffers less from the steric bulk.

Original languageEnglish
Pages (from-to)7-12
Number of pages6
JournalJournal of Organometallic Chemistry
Volume508
Issue number1-2
DOIs
Publication statusPublished - 1996 Feb 8

Keywords

  • Carbonyl
  • Chromium
  • Molybdenum
  • Phosphorus
  • Tungsten
  • X-ray diffraction

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Reactions of ( THF) W( CO) <sub>5</sub> with some diphosphenes carrying bulky aryl and phenoxy groups'. Together they form a unique fingerprint.

  • Cite this