Reactions of o‐bromoacetylacylphenones with several primary amines

Seiko Nan'ya, Hirofumi Ishida, Kiyoshi Kanie, Noriyuki Ito, Yasuo Butsugan

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

o‐Monobromoacetylacylphenones, 3a and 3b reacted with hydroxylamine or hydrazine hydrate to produce heterocycles, 2,3‐benzoxazine or phthalazine derivatives. The reaction of bromoacetyl group of 3a and 3b with several thioamides afforded thiazole derivatives in high yields. Whereas o‐dibromoacetyl‐benzophenoe 2a reacted with aniline or cyclohexylamine to produce non‐heterocycles, 2‐substituted‐iminophenylindanones and the mechanism for the formation of these non‐heterocycles is proposed.

Original languageEnglish
Pages (from-to)1299-1302
Number of pages4
JournalJournal of Heterocyclic Chemistry
Volume32
Issue number4
DOIs
Publication statusPublished - 1995 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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