Reactions of dichlorocarbene with sterically protected 1-phosphaallene and 1,3-diphosphaallene

Masaaki Yoshifuji, Kozo Toyota, Hideki Yoshimura, Ken Hirotsu, Akihiro Okamoto

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

Dichlorocarbene reacted with sterically protected 1-phosphaallene and 1,3-diphosphaallene to give a methylene-phosphirane and a methylene- diphosphirane, respectively; the former phosphirane was converted to 1-phosphabutatriene with butyllithium and the structure of the latter diphosphirane was determined by X-ray crystallography.

Original languageEnglish
Pages (from-to)124-125
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1991 Dec 1

ASJC Scopus subject areas

  • Molecular Medicine

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