Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

Mitsuyoshi Ochiai; Hisako Hashimoto; Hiromi Tobita

doi:10.1039/b819229b

Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

Mitsuyoshi Ochiai, Hisako Hashimoto, Hiromi Tobita

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an α-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.

Original language	English
Pages (from-to)	1812-1814
Number of pages	3
Journal	Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/b819229b
Publication status	Published - 2009 Mar 4

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds",

abstract = "Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an α-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.",

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AU - Ochiai, Mitsuyoshi

AU - Hashimoto, Hisako

AU - Tobita, Hiromi

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Y1 - 2009/3/4

N2 - Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an α-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.

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Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds

Abstract

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