TY - JOUR
T1 - Reaction specificity of a titanium(IV)-porphyrin complex to hydrogen peroxide in view of an ab initio study
AU - Takamura, Kiyoko
AU - Matsubara, Chiyo
AU - Matsumoto, Takatoshi
PY - 2008/3
Y1 - 2008/3
N2 - A Ti-TPyP reagent, i.e. an acidic aqueous solution of oxo[5,10,15,20- tetra(4-pyridyl)porphyrinato]titanium(IV) complex, TiO(tpyp), was previously developed as a highly sensitive and specific reagent for determining hydrogen peroxide. In the present work, the reaction specificity of the TiO(tpyp) complex to hydrogen peroxide was clarified based on ab initio calculations. The results provide a well-grounded argument for determining hydrogen peroxide using the Ti-TPyP reagent experimentally. 2008
AB - A Ti-TPyP reagent, i.e. an acidic aqueous solution of oxo[5,10,15,20- tetra(4-pyridyl)porphyrinato]titanium(IV) complex, TiO(tpyp), was previously developed as a highly sensitive and specific reagent for determining hydrogen peroxide. In the present work, the reaction specificity of the TiO(tpyp) complex to hydrogen peroxide was clarified based on ab initio calculations. The results provide a well-grounded argument for determining hydrogen peroxide using the Ti-TPyP reagent experimentally. 2008
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U2 - 10.2116/analsci.24.401
DO - 10.2116/analsci.24.401
M3 - Article
C2 - 18332550
AN - SCOPUS:48449097012
SN - 0910-6340
VL - 24
SP - 401
EP - 404
JO - Analytical Sciences
JF - Analytical Sciences
IS - 3
ER -