Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen

Shigeru Sasaki

doi:10.1080/10426507.2016.1212344

Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen

Shigeru Sasaki

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Reaction of tris(2,4,6-triisopropylphenyl)phosphine with iodine in air afforded a phosphonium triiodide resulting from the oxidation to the radical cation followed by the reaction with a molecular oxygen and the cyclization with the ortho-isopropyl group.

Original language	English
Pages (from-to)	1513-1514
Number of pages	2
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	191
Issue number	11-12
DOIs	https://doi.org/10.1080/10426507.2016.1212344
Publication status	Published - 2016 Dec 1

Keywords

Phosphine
iodine
oxidation
phosphonium salt
radical cation

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1080/10426507.2016.1212344

Cite this

@article{7f28f6a0d4b84b72b951e313b8944d32,

title = "Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen",

abstract = "Reaction of tris(2,4,6-triisopropylphenyl)phosphine with iodine in air afforded a phosphonium triiodide resulting from the oxidation to the radical cation followed by the reaction with a molecular oxygen and the cyclization with the ortho-isopropyl group.",

keywords = "Phosphine, iodine, oxidation, phosphonium salt, radical cation",

author = "Shigeru Sasaki",

year = "2016",

month = dec,

day = "1",

doi = "10.1080/10426507.2016.1212344",

language = "English",

volume = "191",

pages = "1513--1514",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor and Francis Ltd.",

number = "11-12",

}

TY - JOUR

T1 - Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen

AU - Sasaki, Shigeru

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Reaction of tris(2,4,6-triisopropylphenyl)phosphine with iodine in air afforded a phosphonium triiodide resulting from the oxidation to the radical cation followed by the reaction with a molecular oxygen and the cyclization with the ortho-isopropyl group.

AB - Reaction of tris(2,4,6-triisopropylphenyl)phosphine with iodine in air afforded a phosphonium triiodide resulting from the oxidation to the radical cation followed by the reaction with a molecular oxygen and the cyclization with the ortho-isopropyl group.

KW - Phosphine

KW - iodine

KW - oxidation

KW - phosphonium salt

KW - radical cation

UR - http://www.scopus.com/inward/record.url?scp=84992571493&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84992571493&partnerID=8YFLogxK

U2 - 10.1080/10426507.2016.1212344

DO - 10.1080/10426507.2016.1212344

M3 - Article

AN - SCOPUS:84992571493

VL - 191

SP - 1513

EP - 1514

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

SN - 1042-6507

IS - 11-12

ER -

Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this