Reaction of a sterically crowded triarylphosphine with iodine in the presence of oxygen

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1 Citation (Scopus)

Abstract

Reaction of tris(2,4,6-triisopropylphenyl)phosphine with iodine in air afforded a phosphonium triiodide resulting from the oxidation to the radical cation followed by the reaction with a molecular oxygen and the cyclization with the ortho-isopropyl group.

Original languageEnglish
Pages (from-to)1513-1514
Number of pages2
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume191
Issue number11-12
DOIs
Publication statusPublished - 2016 Dec 1

Keywords

  • Phosphine
  • iodine
  • oxidation
  • phosphonium salt
  • radical cation

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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