2,4-Di-t-butyl-6-methylphenylphosphonous dichloride reacted with chloroform in the presence of lithium diisopropylamide to give (2,4-di-t-butyl-6-methylphenyl)(dichloromethyl)(1,2,2-trichloroethenyl) phosphine. The structure of this phosphine was analyzed by X-ray crystallography. This phosphine further reacted with butyllithium to give (1-butylpentylidene)(2,4-di-t-butyl-6-methylphenyl)phosphine bearing a low-coordinated phosphorus atom.
|Number of pages||5|
|Publication status||Published - 1996 Jan 1|
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