Reaction between rare earth elements and HFNO2 solution

Nobuaki Sato; Akiichi Kigoshi

doi:10.1016/0040-6031(82)80054-3

Reaction between rare earth elements and HFNO₂ solution

Nobuaki Sato, Akiichi Kigoshi

Division of Process and System Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Rare earth elements react with HFNO₂ solution to produce nitrosylium fluorometallates (NO)_xLnF_x+3. The value of x is 1.0 or 1.5 for light rare earth elements and 0.5 or 1.0 for heavy rare earths. Nitrosylium fluorometallates of rare earth elements can be decomposed into the simple fluoride and nitrosyl fluoride at low temperatures (46-68°C).

Original language	English
Pages (from-to)	141-145
Number of pages	5
Journal	Thermochimica Acta
Volume	57
Issue number	2
DOIs	https://doi.org/10.1016/0040-6031(82)80054-3
Publication status	Published - 1982 Sep 1

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

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abstract = "Rare earth elements react with HFNO2 solution to produce nitrosylium fluorometallates (NO)xLnFx+3. The value of x is 1.0 or 1.5 for light rare earth elements and 0.5 or 1.0 for heavy rare earths. Nitrosylium fluorometallates of rare earth elements can be decomposed into the simple fluoride and nitrosyl fluoride at low temperatures (46-68°C).",

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AB - Rare earth elements react with HFNO2 solution to produce nitrosylium fluorometallates (NO)xLnFx+3. The value of x is 1.0 or 1.5 for light rare earth elements and 0.5 or 1.0 for heavy rare earths. Nitrosylium fluorometallates of rare earth elements can be decomposed into the simple fluoride and nitrosyl fluoride at low temperatures (46-68°C).

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