Rationalization of supramolecular chirality in a bisporphyrin system

Victor V. Borovkov; Isao Fujii; Atsuya Muranaka; Guy A. Hembury; Takeyuki Tanaka; Arnout Ceulemans; Nagao Kobayashi; Yoshihisa Inoue

doi:10.1002/anie.200460965

Rationalization of supramolecular chirality in a bisporphyrin system

Victor V. Borovkov, Isao Fujii, Atsuya Muranaka, Guy A. Hembury, Takeyuki Tanaka, Arnout Ceulemans, Nagao Kobayashi, Yoshihisa Inoue

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

A sign of the times: A 1:1 tweezer complex consisting of an achiral bis(zinc porphyrin) and (R,R)-1,2-diaminocyclohexane has been characterized by X-ray crystallographic analysis (see picture, Zn red, N blue). This has enabled a full and unambiguous rationalization of the highly efficient transfer of chirality information from an optically active guest to an achiral host in a supramolecular system based on a bisporphyrin to be carried out.

Original language	English
Pages (from-to)	5481-5485
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	41
DOIs	https://doi.org/10.1002/anie.200460965
Publication status	Published - 2004 Oct 18

Keywords

Chirality
Circular dichroism
Porphyrinoids
Structure elucidation
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200460965

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Rationalization of supramolecular chirality in a bisporphyrin system. / Borovkov, Victor V.; Fujii, Isao; Muranaka, Atsuya; Hembury, Guy A.; Tanaka, Takeyuki; Ceulemans, Arnout; Kobayashi, Nagao; Inoue, Yoshihisa.

In: Angewandte Chemie - International Edition, Vol. 43, No. 41, 18.10.2004, p. 5481-5485.

Research output: Contribution to journal › Article › peer-review

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AU - Tanaka, Takeyuki

AU - Ceulemans, Arnout

AU - Kobayashi, Nagao

AU - Inoue, Yoshihisa

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KW - Circular dichroism

KW - Porphyrinoids

KW - Structure elucidation

KW - Supramolecular chemistry

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Rationalization of supramolecular chirality in a bisporphyrin system

Abstract

Keywords

ASJC Scopus subject areas

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