Raman spectroscopy as a unique tool for characterizing high-Tc superconducting oxides

Masato Kakihana, Minoru Osada, Valery Petrykin

Research output: Contribution to journalConference articlepeer-review

11 Citations (Scopus)


We address our full attention to the various useful capabilities of the Raman scattering technique for characterizing high-Tc superconducting oxides. The powerful aspect of Raman spectroscopy is demonstrated with regard to detection of traces of impurities as compared with the conventional X-ray diffraction technique. Oxygen disordering within CuO chains in Co-doped Y123 type materials is sensitively detected by the Raman scattering technique, the degree of which is proportional to the intensity of the disorder induced Raman mode above 550 cm-1. The phonon Raman spectra of (Pb2Cu)Sr2Y1-xCaxCu2O8+d, (Pb2Cu)Sr0.9La1.1CuO6+d and (Pb0.5Cu0.5)Sr2YCu2O7+d are investigated and phonon assignments compatible with the layer stacking sequences found in these Pb-based cuprates are proposed. Raman scattering can also be used as a means to detect insulator-to-metal transitions in various high-Tc cuprates, an example of which is demonstrated for (Pb2Cu)Sr2Y1-xCaxCu2O8+d; the intensity for the B1g OCu mode abruptly drops across the insulator-to-metal transition as a result of the increased metallic screening in the hole-introduced samples.

Original languageEnglish
Pages (from-to)144-150
Number of pages7
JournalPhysica C: Superconductivity and its applications
Issue number1
Publication statusPublished - 2000 Aug 1
Externally publishedYes
EventInternational Discussion Meeting on Chemistry Approaches to High-Tc Superconductive Materials / 5th International Workshop on Chemical Designing and Processing of High-Tc Superconductors (Chem-HTSC-V) - Yokohama, Jpn
Duration: 1999 Oct 151999 Oct 16

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering


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