Raman-active phonons and their doping dependence in spin-ladder Sr14Cu24O41

M. Osada, M. Kakihana, I. Nagai, T. Noji, T. Adachi, Y. Koike, J. Bäckström, M. Käll, L. Börjesson

Research output: Contribution to journalConference articlepeer-review

6 Citations (Scopus)


Raman spectra of Sr14-xCaxCu24O41 have been investigated in a number of well-defined single-crystal and polycrystalline samples. From the polarization and doping dependence, and from a comparison with previous reports on isostructural compounds, we identify the (4Ag + 4B1g + 3B2g + B3g) modes that are Raman allowed within the simple Fmmm structure, consisting of two Cu-O sub-lattices. With increasing Ca content, we observe the intensity decrease in the modes involving the atoms of the ladders. This effect, analogous to the CuO2-plane phonons in the high-Tc cuprates, can be attributed to the hole transfer from the chains to the ladders.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering


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