Radiochemical Synthesis of New Acetylacetone Complexes of Technetium and Their Properties

Tsutomu Sekine, Kenji Yoshihara

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Three kinds of acetylacetone complexes of technetium were synthesized by the following radiochemical methods; l)99mTcO2(acac)2 by the β- decay in 99MoO2(acac)2; 2) Tc(acac)3 by the (β, p) reaction in Ru(acac)3, and 3) Tc(acac)2 by recoil implantation using (d, xn) reaction in the mixture of molybdenum metal powder and Co(acac)2 ∙ 2 H2O. The technetium acetylacetonates thus produced were purified by vacuum sublimation technique, and some of their properties were investigated.

Original languageEnglish
Pages (from-to)139-142
Number of pages4
JournalRadiochimica Acta
Volume29
Issue number2-3
DOIs
Publication statusPublished - 1981 Jun

Keywords

  • Recoil implantation of Tc
  • Sublimation of radionuclides
  • Technetium acac complexes
  • Thermal stability of TcO2 (acac)2
  • ß-decay effect in 99MoO2(acac)2

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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