Radical ions in fullerene chemistry

Ch Siedschlag, G. Torres-Garcia, Ch Wolff, J. Mattay, M. Fujitsuka, A. Watanabe, O. Ito, L. Dunsch, F. Ziegs, H. Luftmann

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

[60]fullerene is irradiated in the presence of several electron transfer photosensitizers. Upon addition of various H-donors 1-substituted 1,2-dihydro-[60]fullerenes are formed. Mechanistic studies using laser flash photolysis as well as ESR spectroscopy reveal the formation of the radical cation of [60]fullerene. In addition the [2 + 2]photoreactions of 4-methyl-1,2,4-triazoline-3,5-dione (NMTAD) with [60]fullerene derivatives are reported.

Original languageEnglish
Pages (from-to)265-270
Number of pages6
JournalJournal of Information Recording
Volume24
Issue number3-4
Publication statusPublished - 1998 Dec 1

Keywords

  • ESR spectroscopy
  • Laser flash photolysis
  • Photoinduced electron transfer (PET)
  • Radical cation of [60]fullerene, dihydro[60]fullerenes
  • [2 + 2]photocycloaddition

ASJC Scopus subject areas

  • Arts and Humanities(all)

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