Radical-initiator-induced solid-state polymerization of butadiyne nanocrystals in water and their dispersion stabilization

Shuhei Kato, Takahiro Kinemuchi, Yoko Tatewaki, Shuji Okada, Akito Masuhara, Hitoshi Kasai, Hidetoshi Oikawa

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)


    Butadiyne nanocrystals in water are usually polymerized by UV or γ-ray irradiation to give polydiacetylene (PDA) nanocrystals. In this study, we confirmed that solid-state polymerization of 1,6-di(N-carbazolyl)-2,4- hexadiyne (DCHD) and 5,7-dodecadiyn-1,12-diyl bis[N-(butoxycarbonylmethyl) carbamate] (4BCMU) could be stimulated by water-soluble radical initiators. The radical initiators used were potassium peroxodisulfate, three kinds of azo-type compounds and a redox initiator. In all cases, the solid-state polymerization was confirmed by color change into blue indicating that PDA modified by the radical residues at the end was formed. However, nanocrystal cohesion occurred especially when the concentration of the initiators was high or the dispersion was kept for a long time. In order to improve the dispersion stability, two kinds of surfactants, i.e., sodium dodecyl sulfate (SDS) or dodecyltrimethylammonium chloride (DTMAC), were added to the DCHD nanocrystal aqueous dispersion. As a result, when anionic SDS was added, the solid-state polymerization of nanocrystals proceeded without coagulation and quantitative conversion was confirmed for all initiators. Cationic DTMAC has no effect on dispersion stabilization. PDA nanocrystal surfaces in water are negatively charged in nature and electric interaction of nanocrystals with the cations results in decrease of surface charge and aggregation of nanocrystals.

    Original languageEnglish
    Pages (from-to)3340-3344
    Number of pages5
    JournalJournal of Nanoscience and Nanotechnology
    Issue number4
    Publication statusPublished - 2011


    • Nanocrystals
    • Polydiacetylene
    • Radical polymerization
    • Solid-state Polymerization

    ASJC Scopus subject areas

    • Bioengineering
    • Chemistry(all)
    • Biomedical Engineering
    • Materials Science(all)
    • Condensed Matter Physics


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