TY - JOUR
T1 - Quasielastic light scattering in superionic glasses AgI-Ag2O-MoO3
AU - Matsuo, S.
AU - Yugami, H.
AU - Ishigame, M.
N1 - Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 1993
Y1 - 1993
N2 - Quasielastic light scattering (QELS) due to hopping of Ag+ ions was studied on superionic glasses (AgI)x(Ag2OMoO3)1-x (x=0.60,0.70,0.75). The temperature dependence of the QELS intensity at a fixed frequency as well as the integrated QELS intensity were measured. The activation energy for ionic hopping did not depend on glass composition, and the value (0.1 eV) was close to that determined in -AgI. From these results, it was concluded that the local hopping of Ag+ ions in the region like -AgI contributes to QELS. It was found from the temperature dependence of the QELS intensity that the concentration of hopping ions increased with increasing temperature above 220 K. The increase in hopping-ion concentration may be related to a dc conduction process.
AB - Quasielastic light scattering (QELS) due to hopping of Ag+ ions was studied on superionic glasses (AgI)x(Ag2OMoO3)1-x (x=0.60,0.70,0.75). The temperature dependence of the QELS intensity at a fixed frequency as well as the integrated QELS intensity were measured. The activation energy for ionic hopping did not depend on glass composition, and the value (0.1 eV) was close to that determined in -AgI. From these results, it was concluded that the local hopping of Ag+ ions in the region like -AgI contributes to QELS. It was found from the temperature dependence of the QELS intensity that the concentration of hopping ions increased with increasing temperature above 220 K. The increase in hopping-ion concentration may be related to a dc conduction process.
UR - http://www.scopus.com/inward/record.url?scp=35949007725&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=35949007725&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.48.15651
DO - 10.1103/PhysRevB.48.15651
M3 - Article
AN - SCOPUS:35949007725
VL - 48
SP - 15651
EP - 15657
JO - Physical Review B
JF - Physical Review B
SN - 0163-1829
IS - 21
ER -