Quasi one-dimensional organic superconductor MDT-TSF· AuI2 with Tc = 4.5 K at ambient pressure

Kazuo Takimiya, Yoshiro Kataoka, Yoshio Aso, Tetsuo Otsubo, Hiroshi Fukuoka, Shoji Yamanaka

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

The radical cationic salt of methyl enedithiotetraselenafulvalene (MDT-TSF), shown in the picture was formed on its treatment with AuI2-. The salt showed a superconducting transition at 4.5 K (onset) at ambient pressure. The crystal structure of the MDT-TSF cation is completely planar and stacked along its a-axis; the calculated overlap integral is five times greater in the intrastack compared to the interstack direction and the material is therefore quasi one-dimensional.

Original languageEnglish
Pages (from-to)1122-1125
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number6
DOIs
Publication statusPublished - 2001 Mar 14

Keywords

  • Conducting materials
  • Radical ions
  • Selenium
  • Superconductors

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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