Abstract
Thermal reaction of [Ir(Me)(H){η2-Me2Si(CH2) 2PPh2}(PMe3)2] with SiRH3 (R = n-butyl, pentyl or hexyl) resulted in silicon-carbon bond formation to give SiR(Me)H2 and [IrH2{η2-Me2Si(CH2) 2PPh2}(PMe3)2]. Isolation of Si(n-C6H13)MeH2 was achieved by preparative gas chromatography.
Original language | English |
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Pages (from-to) | 3531-3533 |
Number of pages | 3 |
Journal | Journal of the Chemical Society - Dalton Transactions |
Issue number | 19 |
DOIs | |
Publication status | Published - 1997 Oct 7 |
ASJC Scopus subject areas
- Chemistry(all)