Quantitative transfer of a methyl group from a methyl(hydrido)iridium complex to SiRH3 (R = n-butyl, pentyl or hexyl) to give SiR(Me)H2 and a dihydridoiridium complex

Masaaki Okazaki; Hiromi Tobita; Hiroshi Ogino

doi:10.1039/a702439h

Quantitative transfer of a methyl group from a methyl(hydrido)iridium complex to SiRH₃ (R = n-butyl, pentyl or hexyl) to give SiR(Me)H₂ and a dihydridoiridium complex

Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Thermal reaction of [Ir(Me)(H){η²-Me₂Si(CH₂) ₂PPh₂}(PMe₃)₂] with SiRH₃ (R = n-butyl, pentyl or hexyl) resulted in silicon-carbon bond formation to give SiR(Me)H₂ and [IrH₂{η²-Me₂Si(CH₂) ₂PPh₂}(PMe₃)₂]. Isolation of Si(n-C₆H₁₃)MeH₂ was achieved by preparative gas chromatography.

Original language	English
Pages (from-to)	3531-3533
Number of pages	3
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/a702439h
Publication status	Published - 1997 Oct 7

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Chemistry(all)

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Quantitative transfer of a methyl group from a methyl(hydrido)iridium complex to SiRH₃ (R = n-butyl, pentyl or hexyl) to give SiR(Me)H₂ and a dihydridoiridium complex. / Okazaki, Masaaki; Tobita, Hiromi; Ogino, Hiroshi.

In: Journal of the Chemical Society - Dalton Transactions, No. 19, 07.10.1997, p. 3531-3533.

Research output: Contribution to journal › Article › peer-review

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abstract = "Thermal reaction of [Ir(Me)(H){η2-Me2Si(CH2) 2PPh2}(PMe3)2] with SiRH3 (R = n-butyl, pentyl or hexyl) resulted in silicon-carbon bond formation to give SiR(Me)H2 and [IrH2{η2-Me2Si(CH2) 2PPh2}(PMe3)2]. Isolation of Si(n-C6H13)MeH2 was achieved by preparative gas chromatography.",

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AU - Tobita, Hiromi

AU - Ogino, Hiroshi

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Y1 - 1997/10/7

N2 - Thermal reaction of [Ir(Me)(H){η2-Me2Si(CH2) 2PPh2}(PMe3)2] with SiRH3 (R = n-butyl, pentyl or hexyl) resulted in silicon-carbon bond formation to give SiR(Me)H2 and [IrH2{η2-Me2Si(CH2) 2PPh2}(PMe3)2]. Isolation of Si(n-C6H13)MeH2 was achieved by preparative gas chromatography.

AB - Thermal reaction of [Ir(Me)(H){η2-Me2Si(CH2) 2PPh2}(PMe3)2] with SiRH3 (R = n-butyl, pentyl or hexyl) resulted in silicon-carbon bond formation to give SiR(Me)H2 and [IrH2{η2-Me2Si(CH2) 2PPh2}(PMe3)2]. Isolation of Si(n-C6H13)MeH2 was achieved by preparative gas chromatography.

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Quantitative transfer of a methyl group from a methyl(hydrido)iridium complex to SiRH₃ (R = n-butyl, pentyl or hexyl) to give SiR(Me)H₂ and a dihydridoiridium complex

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