Abstract
As an analytical application for pyrochemical reprocessing using molten salts, quantitative analysis of uranium and lanthanides by UV/Vis/NIR absorption spectrophotometry was performed. Electronic absorption spectra of LiCl-KCl eutectic at 773 K including trivalent uranium and eight rare earth elements (Y, La, Ce, Pr, Nd, Sm, Eu, and Gd as fission product elements) were measured in the wavenumber region of 4,500-33,000 cm-1. The composition of the solutes was simulated for a reductive extraction condition in a pyroreprocessing process for spent nuclear fuels, that is, about 2 wt% U and 0.1-2 wt% rare earth elements. Since U(III) possesses strong absorption bands due to f-d transitions, an optical quartz cell with short light path length of 1 mm was adopted in the analysis. The quantitative analysis of trivalent U, Nd, Pr, and Sm was possible with their f-f transition intensities in the NIR region. The analytical results agree with the prepared concentrations within 2σ experimental uncertainties.
| Original language | English |
|---|---|
| Pages (from-to) | 255-259 |
| Number of pages | 5 |
| Journal | Journal of Radioanalytical and Nuclear Chemistry |
| Volume | 296 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2013 Apr 1 |
Keywords
- Absorption spectrophotometry
- Chloride
- Lanthanide
- Molten salt
- Pyroreprocessing
- Uranium
ASJC Scopus subject areas
- Analytical Chemistry
- Nuclear Energy and Engineering
- Radiology Nuclear Medicine and imaging
- Pollution
- Spectroscopy
- Public Health, Environmental and Occupational Health
- Health, Toxicology and Mutagenesis