Proton dynamics of the water lattice in nanochannel

H. Matsui, Y. Suzuki, H. Fukumochi, M. Tadokoro

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

By the microwave and infrared measurements, the water nanotube encapsulated in the nanochannel framework of molecular porous crystal exhibits intrinsic proton conduction with high conductivity and activation behavior. Self-dissociation of water molecules generates protons and protonic holes forming an Eigen-type hydrate with local distortions. One-dimensional water chain is constructed in the similar porous crystal with narrower nanochannel size. The microwave response comes from protons and protonic holes respectively combined with mobile D and L configurational defects traveling on the water chain, which is influenced by the anisotropic Coulomb fields due to Co3+ in the framework.

Original languageEnglish
Title of host publication2014 39th International Conference on Infrared, Millimeter, and Terahertz Waves, IRMMW-THz 2014
PublisherIEEE Computer Society
ISBN (Electronic)9781479938773
DOIs
Publication statusPublished - 2014 Nov 13
Event39th International Conference on Infrared, Millimeter and Terahertz Waves, IRMMW-THz 2014 - Tucson, United States
Duration: 2014 Sep 142014 Sep 19

Publication series

NameInternational Conference on Infrared, Millimeter, and Terahertz Waves, IRMMW-THz
ISSN (Print)2162-2027
ISSN (Electronic)2162-2035

Other

Other39th International Conference on Infrared, Millimeter and Terahertz Waves, IRMMW-THz 2014
CountryUnited States
CityTucson
Period14/9/1414/9/19

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering

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