Property design of Bi4Ti3O12-based thin films using a site-engineered concept

H. Funakubo, T. Watanabe, T. Kojima, T. Sakai, Y. Noguchi, M. Miyayama, M. Osada, M. Kakihana, K. Saito

Research output: Contribution to journalConference articlepeer-review

36 Citations (Scopus)


A property design concept involving the substitution of each crystal site in the pseudoperovskite in Bi4Ti3O12 structure, a site-engineered concept, is proposed for Bi4Ti3O12-based thin films. This concept is based on the selective substitution of each crystal site contributing to the ferroelectric properties. By using this concept, a novel material, i.e. (Bi,Nd)4(Ti,V)3O12 was developed. A remnant polarization (Pr) value above 16 μC/cm2 at a process temperature of 540°C was obtained together with orientation control of the films. This Pr value is comparable to that of the widely used Pb-based ferroelectrics, such as Pb(Zr,Ti)O3.

Original languageEnglish
Pages (from-to)180-185
Number of pages6
JournalJournal of Crystal Growth
Issue numberSUPPL.
Publication statusPublished - 2003 Feb
Externally publishedYes
EventProceedings of the eleventh international conference on MOVPE XI - Berlin, Germany
Duration: 2002 Jun 32002 Jun 7


  • A3. Metal organic chemical vapor deposition phase
  • B1. Oxide
  • B2. Ferroelectric materials

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Materials Chemistry


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