Production of cellulose-derived olefins and applicability to gasoline

Yasuyo Okuyama; Mitsuru Koike; Shinya Sasaki; Sibao Liu; Masazumi Tamura; Yoshinao Nakagawa; Akio Imai; Keiichi Tomishige

doi:10.1627/jpi.59.228

Production of cellulose-derived olefins and applicability to gasoline

Yasuyo Okuyama, Mitsuru Koike, Shinya Sasaki, Sibao Liu, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A gasoline-boiling-range olefin production process which combines hexanol production from cellulose using Ir-ReO_x/SiO₂ and acid catalysts and hexene production from the hexanol using H-ZSM-5 catalyst is proposed. The compositions of the hexene mixture obtained by dehydrating 1- 2- and 3-hexanol and the applicability of the mixture to gasoline based on JIS specifications were determined. About 22 vol.% and ca. 7 vol.% of the hexene mixture could be blended into regular gasoline in summer and winter respectively. This suggests that the hexene mixture obtained from cellulose through this pathway is a potential biofuel.

Original language	English
Pages (from-to)	228-234
Number of pages	7
Journal	Journal of The Japan Petroleum Institute
Volume	59
Issue number	5
DOIs	https://doi.org/10.1627/jpi.59.228
Publication status	Published - 2016

Keywords

Biogasoline
Cellulose-derived olefin
Dehydration
Hexanol
Hexene

ASJC Scopus subject areas

Fuel Technology
Energy Engineering and Power Technology

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10.1627/jpi.59.228

Cite this

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abstract = "A gasoline-boiling-range olefin production process which combines hexanol production from cellulose using Ir-ReOx/SiO2 and acid catalysts and hexene production from the hexanol using H-ZSM-5 catalyst is proposed. The compositions of the hexene mixture obtained by dehydrating 1- 2- and 3-hexanol and the applicability of the mixture to gasoline based on JIS specifications were determined. About 22 vol.% and ca. 7 vol.% of the hexene mixture could be blended into regular gasoline in summer and winter respectively. This suggests that the hexene mixture obtained from cellulose through this pathway is a potential biofuel.",

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T1 - Production of cellulose-derived olefins and applicability to gasoline

AU - Okuyama, Yasuyo

AU - Koike, Mitsuru

AU - Sasaki, Shinya

AU - Liu, Sibao

AU - Tamura, Masazumi

AU - Nakagawa, Yoshinao

AU - Imai, Akio

AU - Tomishige, Keiichi

PY - 2016

Y1 - 2016

N2 - A gasoline-boiling-range olefin production process which combines hexanol production from cellulose using Ir-ReOx/SiO2 and acid catalysts and hexene production from the hexanol using H-ZSM-5 catalyst is proposed. The compositions of the hexene mixture obtained by dehydrating 1- 2- and 3-hexanol and the applicability of the mixture to gasoline based on JIS specifications were determined. About 22 vol.% and ca. 7 vol.% of the hexene mixture could be blended into regular gasoline in summer and winter respectively. This suggests that the hexene mixture obtained from cellulose through this pathway is a potential biofuel.

AB - A gasoline-boiling-range olefin production process which combines hexanol production from cellulose using Ir-ReOx/SiO2 and acid catalysts and hexene production from the hexanol using H-ZSM-5 catalyst is proposed. The compositions of the hexene mixture obtained by dehydrating 1- 2- and 3-hexanol and the applicability of the mixture to gasoline based on JIS specifications were determined. About 22 vol.% and ca. 7 vol.% of the hexene mixture could be blended into regular gasoline in summer and winter respectively. This suggests that the hexene mixture obtained from cellulose through this pathway is a potential biofuel.

KW - Biogasoline

KW - Cellulose-derived olefin

KW - Dehydration

KW - Hexanol

KW - Hexene

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JO - Sekiyu Gakkaishi (Journal of the Japan Petroleum Institute)

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Production of cellulose-derived olefins and applicability to gasoline

Abstract

Keywords

ASJC Scopus subject areas

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