Probing the reactivity of a stable silene using muonium

Brett M. McCollum; Takashi Abe; Jean Claude Brodovitch; Jason A.C. Clyburne; Takeaki Iwamoto; Mitsuo Kira; Paul W. Percival; Robert West

doi:10.1002/anie.200804458

Probing the reactivity of a stable silene using muonium

Brett M. McCollum, Takashi Abe, Jean Claude Brodovitch, Jason A.C. Clyburne, Takeaki Iwamoto, Mitsuo Kira, Paul W. Percival, Robert West

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

(Chemical Equation Presented) Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1-CMu and 1-SiMu, allowing the relative reactivity of silenic carbon and silicon atoms to be probed. The former is the first reported example of a muoniated silyl radical. The radical species are detected by muon spin rotation and resonance spectroscopy (μSR).

Original language	English
Pages (from-to)	9772-9774
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200804458
Publication status	Published - 2008 Dec 1

Keywords

Muonium
Radicals
Reactivity
Silanes
Silenes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200804458

Cite this

@article{09455c0403ca4e6783a527a19f9abf00,

title = "Probing the reactivity of a stable silene using muonium",

abstract = "(Chemical Equation Presented) Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1-CMu and 1-SiMu, allowing the relative reactivity of silenic carbon and silicon atoms to be probed. The former is the first reported example of a muoniated silyl radical. The radical species are detected by muon spin rotation and resonance spectroscopy (μSR).",

keywords = "Muonium, Radicals, Reactivity, Silanes, Silenes",

author = "McCollum, {Brett M.} and Takashi Abe and Brodovitch, {Jean Claude} and Clyburne, {Jason A.C.} and Takeaki Iwamoto and Mitsuo Kira and Percival, {Paul W.} and Robert West",

year = "2008",

month = dec,

day = "1",

doi = "10.1002/anie.200804458",

language = "English",

volume = "47",

pages = "9772--9774",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "50",

}

TY - JOUR

T1 - Probing the reactivity of a stable silene using muonium

AU - McCollum, Brett M.

AU - Abe, Takashi

AU - Brodovitch, Jean Claude

AU - Clyburne, Jason A.C.

AU - Iwamoto, Takeaki

AU - Kira, Mitsuo

AU - Percival, Paul W.

AU - West, Robert

PY - 2008/12/1

Y1 - 2008/12/1

N2 - (Chemical Equation Presented) Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1-CMu and 1-SiMu, allowing the relative reactivity of silenic carbon and silicon atoms to be probed. The former is the first reported example of a muoniated silyl radical. The radical species are detected by muon spin rotation and resonance spectroscopy (μSR).

AB - (Chemical Equation Presented) Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1-CMu and 1-SiMu, allowing the relative reactivity of silenic carbon and silicon atoms to be probed. The former is the first reported example of a muoniated silyl radical. The radical species are detected by muon spin rotation and resonance spectroscopy (μSR).

KW - Muonium

KW - Radicals

KW - Reactivity

KW - Silanes

KW - Silenes

UR - http://www.scopus.com/inward/record.url?scp=57049153440&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=57049153440&partnerID=8YFLogxK

U2 - 10.1002/anie.200804458

DO - 10.1002/anie.200804458

M3 - Article

C2 - 18988220

AN - SCOPUS:57049153440

VL - 47

SP - 9772

EP - 9774

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 50

ER -

Probing the reactivity of a stable silene using muonium

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this