Probing the reactivity of a stable silene using muonium

Brett M. McCollum; Takashi Abe; Jean Claude Brodovitch; Jason A.C. Clyburne; Takeaki Iwamoto; Mitsuo Kira; Paul W. Percival; Robert West

doi:10.1002/anie.200804458

Probing the reactivity of a stable silene using muonium

Brett M. McCollum, Takashi Abe, Jean Claude Brodovitch, Jason A.C. Clyburne, Takeaki Iwamoto, Mitsuo Kira, Paul W. Percival, Robert West

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

(Chemical Equation Presented) Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1-CMu and 1-SiMu, allowing the relative reactivity of silenic carbon and silicon atoms to be probed. The former is the first reported example of a muoniated silyl radical. The radical species are detected by muon spin rotation and resonance spectroscopy (μSR).

Original language	English
Pages (from-to)	9772-9774
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200804458
Publication status	Published - 2008 Dec 1

Keywords

Muonium
Radicals
Reactivity
Silanes
Silenes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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AU - Brodovitch, Jean Claude

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AU - Iwamoto, Takeaki

AU - Kira, Mitsuo

AU - Percival, Paul W.

AU - West, Robert

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KW - Reactivity

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