Probing the phonon-assisted relaxation processes in DNA-wrapped carbon nanotubes using photoluminescence spectroscopy

S. G. Chou, F. Plentz, J. Jiang, R. Saito, D. Nezich, H. B. Ribeiro, A. Jorio, M. A. Pimenta, Ge G. Samsonidze, A. P. Santos, M. Zheng, G. B. Onoa, E. D. Semke, G. Dresselhaus, M. S. Dresselhaus

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We present a detailed photoluminescence study of a (6,5) enriched DNA-wrapped single wall carbon nanotube (DNA-CNT) solid sample and an as-produced DNA-CNT solution. Multiple strong PL peaks were observed at excitation energies that do not correspond to the interband electronic transitions that are strongly enhanced by electronic van Hove singularities. These strong PL peaks are assigned to different mechanisms of excitation and relaxation, including one phonon, two phonon, hot luminescence processes, as well as radiative and non-radiative energy transferring mechanisms between neighboring nanotubes. These processes are assigned to different channels of phonon-assisted electron relaxation. The study shows that the electronic relaxation processes observed in PL can be used as a means to probe different physical interactions between photons, electrons, and phonons that are not separately identified in bulk semiconducting materials.

Original languageEnglish
Title of host publicationFunctional Carbon Nanotubes
PublisherMaterials Research Society
Pages271-276
Number of pages6
ISBN (Print)1558998101, 9781558998100
DOIs
Publication statusPublished - 2004
Event2004 MRS Fall Meeting - Boston, MA, United States
Duration: 2004 Nov 292004 Dec 2

Publication series

NameMaterials Research Society Symposium Proceedings
Volume858
ISSN (Print)0272-9172

Other

Other2004 MRS Fall Meeting
Country/TerritoryUnited States
CityBoston, MA
Period04/11/2904/12/2

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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