Probability of spontaneously resolvable conglomerates for racemic acid/racemic amine salts predicted on the basis of the results of diastereomeric resolutions

Kazushi Kinbara, Yoshiyuki Tagawa, Kazuhiko Saigo

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

The salts of racemic acids with racemic amines, of which the enantiopure component is a good resolving agent for the corresponding counterpart in diastereomeric resolution, have an extremely high tendency to be conglomerates: the results of diastereomeric resolutions are highly informative for the prediction of conglomerates, which can be enantioseparated by preferential crystallization developed independently from diastereomeric resolution over one and a half centuries.

Original languageEnglish
Pages (from-to)2927-2930
Number of pages4
JournalTetrahedron Asymmetry
Volume12
Issue number21
DOIs
Publication statusPublished - 2001 Nov 26

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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