Preparation, structure and properties of [Na(cis-anti-cis-dicyclohexyl- 18-crown-6)][Ni(dmit)2]4 · 2Me2CO

Neil Robertson, Tomoyuki Akutagawa, Takayoshi Nakamura, Stefan Roehrs, Allan E. Underhill

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The salt [Na(cis-anti-cis-dicyclohexyl-18-crown-6)][Ni(dmit)2]4 · 2Me2CO (dmit=1,3-dithiol-2-thione-4,5-dithiolate) has been prepared by electrocrystallisation and characterised by X-ray crystallography showing an unusual 1:4 cation: anion ratio. It consists of parallel stacks of [Ni(dmit)2]0.25- complexes separated by the Na+ counter ion complexed by dicyclohexyl-18-crown-6 and two acetone molecules. The electrical conductivity, magnetic susceptibility and thermoelectric power of the salt have been measured and are consistent with semiconductor behaviour which is considered in conjunction with transfer integral calculations.

Original languageEnglish
Pages (from-to)1233-1236
Number of pages4
JournalJournal of Materials Chemistry
Volume9
Issue number6
DOIs
Publication statusPublished - 1999 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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