Preparation of thin single crystals of diacetylene by pseudo-homo epitaxy

Kyoji Komatsu, Katsumichi Ono, Hachiro Nakanishi, Hidetoshi Oikawa, Shuji Okada, Hiro Matsuda, Nobutsugu Minami, Yasuhiro Hattori

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2 Citations (Scopus)

Abstract

Thin single-crystal growth of diacetylene monomer between a substrate and a glass plate has been investigated from the molten state. Among five different substrates examined, polydiacetylene single crystal, having the characteristics of pseudo-homo epitaxy, attained the best performance of growth control to give thin single crystals with the size of over one mm2 as well as uniaxial orientation. The crystals were successfully converted into polymer thin single crystals, which were usefull enough for nonlinear optical device fabrication.

Original languageEnglish
Pages (from-to)L1498-L1499
JournalJapanese journal of applied physics
Volume31
Issue number10
DOIs
Publication statusPublished - 1992 Oct

Keywords

  • 2, 4-hexadiynylene bis(p-toluenesulfonate)
  • Diacetylene
  • Epitaxy
  • Polydiacetylene
  • Single thin crystal
  • Solid-state polymerization

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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    Komatsu, K., Ono, K., Nakanishi, H., Oikawa, H., Okada, S., Matsuda, H., Minami, N., & Hattori, Y. (1992). Preparation of thin single crystals of diacetylene by pseudo-homo epitaxy. Japanese journal of applied physics, 31(10), L1498-L1499. https://doi.org/10.1143/JJAP.31.L1498